Preparation and characterization of two triphenylphosphineiron carbonyl complexes: X-ray crystallographic studies of (1–4-η-5-exo-benzylcyclopenta-1,3-diene)dicarbonyl(triphenylphosphine)iron(0), (1), and dicarbonyl(η-cyclopentadienyl)(triphenylphosphine)iron(II) 1,1,2,3,3-pentacyanopropenide, (2)
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 629-635
- https://doi.org/10.1039/dt9790000629
Abstract
The complex [Fe(CH2Ph)(η-C5H5)(CO)2] undergoes a photochemical reaction with PPh3 to yield (1), which has been treated with tetracyanoethylene to yield (2). The products (1) and (2) have been identified and characterized by X-ray crystallography.Keywords
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