High nuclearity carbido carbonyl clusters of rhenium. Synthesis, X-ray crystal structure, and 13C n.m.r. study of the anion [Re8C(CO)24]2?
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 705-706
- https://doi.org/10.1039/c39820000705
Abstract
The novel high nuclearity carbido carbonyl anion [Re8C(CO)24]2–, isolated from the pyrolysis of [ReH2(CO)4]– in n-tetradecane, has the, metal atoms arranged as an octaheron capped on two opposite faces as shown by an X-ray crystal structure determination; 13C n.m.r. analysis has confirmed the nature of the interstitial atom and shown that the solid-state structure of the anion is maintained in solution.Keywords
This publication has 0 references indexed in Scilit: