Free radical chemistry. Part 4. Stereoelectronic effects in the additions of cyclic ethers to fluorinated alkenes
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2215-2218
- https://doi.org/10.1039/p19850002215
Abstract
Free-radical additions of cyclic ethers to various fluorinated alkenes have been studied and a clear stereoelectronic effect has been established. The order of reactivity is oxolane > oxepane > oxane and increasing substitution at the double bond leads to lower reactivity of the fluorinated alkene with oxolane.Keywords
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