Reinvestigation of the Addition of Methylmagnesium Iodide to the Benzoylformate of Enantiomerically Pure 1,1′-Binaphthyl-2-ol Prepared by Enzymatic Kinetic Resolution
- 1 July 1989
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (7) , 1135-1136
- https://doi.org/10.1246/cl.1989.1135
Abstract
A lipase from pseudomonas was found to catalyze almost completely enantioselective hydrolysis of the valerate of racemic 1,1′-binaphthyl-2-ol (1). The Prelog’s atrolactic acid synthesis by use of (aR)-1 induced S-chirality with much lower levels of optical yields (3–17%) than that reported previously (85%).This publication has 6 references indexed in Scilit:
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