Centrifugal and Coriolis effects on level cluster patterns for T (ν3) rovibrational bands in spherical top molecules
- 1 December 1978
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 69 (11) , 4896-4907
- https://doi.org/10.1063/1.436520
Abstract
Fundamental T (ν3) type high‐J rovibrational fine structure is derived for a range of values of the Coriolis and [2×2]4 centrifugal constants. The theory of level clusters is developed further. Correlations are made between cluster states corresponding to well separated P+, Q0, and R− branches, and the opposite case in which Π± and Σ0 labels are appropriate.Keywords
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