Aromatic hydroxylation by O(3P) atoms on γ-radiolysis of liquid carbon dioxide solutions of alkylbenzenes
- 1 January 1978
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 16-18
- https://doi.org/10.1039/c39780000016
Abstract
Hydroxylated products have been produced by the attack of O(3P) atoms, generated by γ-radiolysis of liquid CO2, on alkylbenzene at the following sites: aromatic methine carbon, aromatic ring carbon bearing a substituent accompanied by 1,2-shift of the substituent (NIH shift) or removal of the substituent, and alkyl substituent.Keywords
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