Kinetics of an associative ligand exchange process: alcohol exchange with arsenate(V) and vanadate(V) esters
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 429-430
- https://doi.org/10.1039/c39760000429
Abstract
Alcohol exchange with trialkyl arsenates and vanadates is rapid and appears to proceed via a 5-coordinate transition state wherein the degree of bond-breaking is governed by the steric size of the alkyl group.Keywords
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