New syntheses of mixed peroxides under Gif–Barton oxidation of alkylbenzenes, conjugated alkenes and alkanes; a free-radical mechanism
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1823-1824
- https://doi.org/10.1039/c39940001823
Abstract
Syntheses of mixed peroxides are performed under Gif oxidation of alkylaromatics, electron-rich conjugated alkenes (styrene, α-methylstyrene) or cyclohexane and acrylonitrile; chemical and kinetic evidence support a free-radical redox chain mechanism.Keywords
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