Preparation and study of dinuclear zinc(II) complex for the efficient hydrolysis of the phosphodiester linkage in a diribonucleotide
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1793-1794
- https://doi.org/10.1039/c39950001793
Abstract
A dinuclear zinc(II) complex with N,N,N′,N′-tetrakis[(2-pyridyl)methyl]-2-hydroxy-1,3-diaminopropane efficiently hydrolyses ApA [adenylyl(3′-5′)adenosine] at pH 7 and 50 °C; the complex can thus be regarded as a good artificial ribonuclease which effectively mimics enzyme active sites.Keywords
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