Ab initio computation of radiative lifetimes of the H2 molecule in the nonadiabatically coupled J=1 states derived from {E F+G K+H H̄} 1Σ+g+I 1Πg
- 1 May 1984
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 80 (9) , 4355-4362
- https://doi.org/10.1063/1.447267
Abstract
The vibrational matrix elements of the electronic dipole moments for the transitions (EF, GK, HH̄, I)→(B, C, B′) have been computed in the adiabatic approximation and they have been transformed according to a nonadiabatic representation of the radially and angularly coupled J=1 states of the initial 1∑+g and 1Πg states. The corresponding probabilities for spontaneous emission and the radiative lifetimes are computed and compared with experimental data.Keywords
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