Influence of alkyltrimethyl ammonium halides on the stability of potassium ethyl xanthate in aqueous solution
- 1 March 1969
- journal article
- research article
- Published by Wiley in Journal of Chemical Technology & Biotechnology
- Vol. 19 (3) , 73-76
- https://doi.org/10.1002/jctb.5010190303
Abstract
A study has been made of the stability of potassium ethyl xanthate in solutions containing alkyltrimethyl ammonium halides. It has been shown that the presence of these compounds leads to an increased rate of decomposition, if the solution is in contact with an atmosphere that contains oxygen and its pH is between 6 and 12. Under other conditions, the stability of the xanthate is unaffected by the presence of the co‐solute. It is concluded that the quaternary ammonium compounds catalyse reaction between oxygen and xanthate, and it suggested that at least two different types of oxygenative reaction take place.Keywords
This publication has 3 references indexed in Scilit:
- Complexes Formed by Quaternary Ammonium Salts with Xanthates, and Synergistic Effects in Adsorption of Xanthate Ions on Reduced Copper PowdersSeparation Science, 1966
- SPECTROPHOTOMETRIC STUDY OF XANTHATE AND DIXANTHOGEN SOLUTIONSCanadian Journal of Chemistry, 1963
- Dilute Solutions of Amphipathic Ions. III. Conductivity of Weak SaltsThe Journal of Physical Chemistry, 1958