Synthesis and reactions of t-butyltellurocarbonyloxyalkanes
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 645-647
- https://doi.org/10.1039/c39790000645
Abstract
Reaction of t-butyl(chloromethylene)dimethyl-ammonium chloride with alcohols and sodium hydrogen telluride gave t-butyltellurocarbonyloxyalkanes; 3β-t-butyltellurocarbonyloxy-5α-cholestane [ButC(=Te)OR] with diphenylseleninic anhydride and sodium hydrogen telluride gave, respectively, esters (ButCO2R) and ethers (ButCH2OR) and [(ButCHOR)2].Keywords
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