Synthesis, Characterisation and Antifungal Activity of Ru(III) Complexes with Heterocyclic Dithiocarbamates
- 1 November 1996
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 26 (10) , 1677-1690
- https://doi.org/10.1080/00945719608004400
Abstract
Several new hexa-coordinated ruthenium(III) complexes of the type [RuX2(EPh3)2(LL′)], (X = Cl or Br; E = P or As) [where LL′ = morpholinedithiocarbamate (Morphdtc), piperidinedithiocarbamate (Pipdtc) and piperazinedithio-carbamate (Pzdtc) have been synthesised. In all these complexes the heterocyclic dithiocarbamates behave as a uninegative bidentate (SS) chelating ligand. It has been observed that the incoming ligand replaces a halide, a tertiary phosphine/arsine and methanol from the starting complexes. All the complexes have been characterised on the basis of analytical and spectroscopic data. The new complexes showed a reasonable amount of antifungal activities.Keywords
This publication has 22 references indexed in Scilit:
- Thiosemicarbazone complexes of copper(II): structural and biological studiesCoordination Chemistry Reviews, 1993
- Transition metal complexes with 2-methyl-, 3-methyl-, and 4-methyl-piperidine dithiocarbamate as ligandsTransition Metal Chemistry, 1985
- Structureactivity relationship with therapeutic chelating agentsInorganica Chimica Acta, 1983
- Synthesis and characterization of ruthenium dithiocarbamate complexesJournal of Inorganic and Nuclear Chemistry, 1979
- Mixed complexes of ruthenium(III) and ruthenium(II) with triphenylphosphine or triphenylarsine and other ligandsJournal of Inorganic and Nuclear Chemistry, 1977
- Transition metal complexes of piperazinedithiocarbamateJournal of Inorganic and Nuclear Chemistry, 1976
- Some triorganotin(IV) DithiocarbamatesJournal of Organometallic Chemistry, 1976
- Five-coordinate Bromobis(dialkyldithiocarbamate) Complexes of Arsenic, Antimony, and BismuthCanadian Journal of Chemistry, 1975
- Some ruthenium(III) complexes with triphenylarsineInorganic and Nuclear Chemistry Letters, 1974
- New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligandsJournal of Inorganic and Nuclear Chemistry, 1966