NaV3(OH)6(SO4)2: A Kagomé-Type Vanadium(III) Compound with Strong Intralayer Ferromagnetic Interactions
- 17 April 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (8) , 1519-1521
- https://doi.org/10.1002/1521-3773(20010417)40:8<1519::aid-anie1519>3.0.co;2-d
Abstract
A dominant ferromagnetic exchange interaction propagates about the magnetic sites of the Kagomé lattice of the title compound through the bridging hydroxy groups (see section of the structure). This is at variance with the antiferromagnetic exchange observed for jarosite and its derivatives. The ferromagnetism probably arises from the d2 electron count of the VIII centers.This publication has 23 references indexed in Scilit:
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