Short-range versus long-range electron-hole exchange interactions in semiconductor quantum dots

Abstract
Using a many-body approach based on atomistic pseudopotential wave functions we show that the electron-hole exchange interaction in semiconductor quantum dots is characterized by a large, previously neglected long-range component, originating from monopolar interactions of the transition density between different unit cells. The calculated electron-hole exchange splitting of CdSe and InP nanocrystals is in good agreement with recent experimental measurements.