Polymerization of Diene and Diyne Monomers in Deoxycholic and Apocholic Acid Inclusion Compounds
- 1 August 1990
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics
- Vol. 186 (1) , 189-195
- https://doi.org/10.1080/00268949008037210
Abstract
One-dimensional polymerization of conjugated diene and diyne monomers in channels of deoxycholic and apocholic acid inclusion compounds is discussed. The polymerization exhibited the following remarkable features on the basis of a one-dimensional character of the molecular assemblies, in contrast to that in solution or the solid state: (i) stabilized propagating radicals, (ii) decreased reaction rates, and (iii) an efficient induction of regiospecificity and stereo-specificity.Keywords
This publication has 22 references indexed in Scilit:
- Size, shape, and site selectivities in the photochemical reactions of molecules adsorbed on pentasil zeolites. Effects of coadsorbed waterJournal of the American Chemical Society, 1987
- Functional monomers and polymers. CXLII Inclusion polymerization of diene monomers in deoxycholic acid and apocholic acid canals by free radical initiatorsJournal of Polymer Science Part C: Polymer Letters, 1986
- Deuterium nuclear magnetic resonance study of solid deoxycholic acid adducts: structure, dynamics, and photochemical reactivityThe Journal of Physical Chemistry, 1985
- Photochemical reaction of inclusion molecular complexes of N,N-dialkylpyruvamides with desoxycholic acid. Host-controlled reaction of guest compounds in the solid stateJournal of the Chemical Society, Chemical Communications, 1983
- An ESR study of intrachannel mobility in DOCA clathrates. Effects due to photochemical reactivity between guest and hostThe Journal of Physical Chemistry, 1982
- Effect of mass perturbations on the LA mode of polymers: Surface bromination of polyethylene crystalsJournal of Macromolecular Science, Part B, 1980
- ESR Studies on Radiation-Induced Polymerization of 1,3-Butadiene in Urea Canal ComplexesBulletin of the Chemical Society of Japan, 1973
- Asymmetric synthesis. Radiation polymerization of trans-1,3-pentadiene included in optically active perhydrotriphenyleneJournal of the American Chemical Society, 1967
- Stereospecific Polymerization in Urea Canal Complexes1Journal of the American Chemical Society, 1960
- Stereospecific Polymerization in Thiourea Canal Complexes1Journal of the American Chemical Society, 1960