An infrared study of gallium chlorides and bromides in benzene and n-heptane

1 January 1968

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 969-972
https://doi.org/10.1039/j19680000969

Abstract

Infrared spectra, over the range 500–200 cm.^–1, were recorded for benzene solutions of gallium dichloride and gallium dibromide prepared by the method of Carlston and his co-workers, for solutions of the corresponding trihalides (Ga₂Cl₆ and Ga₂Br₆) in benzene and n-heptane, and also for hydrolysed solutions of the dihalides and trihalides. Assignments are made for the gallium trihalides in accordance with previous work and for the dihalides on the basis of a postulated ion-pair structure.

Keywords

GALLIUM
STRUCTURE
HEPTANE
BENZENE
CARLSTON
WORKERS
MADE
SPECTRA
POSTULATED
GA2CL6

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