On the conditions for C-6 epimerization of the penicillin nucleus by a β-elimination mechanism
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 17,p. 1067-1068
- https://doi.org/10.1039/c29700001067
Abstract
The effects of temperature, the substitution pattern at C-5 and C-6, and the base are employed to delineate the conditions for proton abstraction from C-6 of the penicillin nucleus by carbanion or β-elimination pathways.Keywords
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