Aminolysis of Activated Esters Formed by Reaction of Carboxylate Salts with Strained Phosphonates and Phosphinates
- 1 November 1982
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 55 (11) , 3675-3676
- https://doi.org/10.1246/bcsj.55.3675
Abstract
Nucleophilic attack of a carboxylate salt on a five-membered phosphonic or phosphinic ester followed by an intramolecular acyl transfer reaction gives a substituted aryl ester. Due to the intramolecular base catalysis of a neighbouring P=O group the bimolecular aminolysis of this ester is a fast process.This publication has 1 reference indexed in Scilit:
- Aminolysis reactions. II. Catalysis of esteraminolysis in chlorobenzene. Correlation with hydrogen-bonding ability of catalystsJournal of the American Chemical Society, 1974