The effect of charge-transfer interactions on the photochemical reaction of 2-vinylnaphthalene
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 64-65
- https://doi.org/10.1039/c39840000064
Abstract
Charge-transfer interactions between 2-vinylnaphthalene (VN) in the excited singlet state and amines in the ground state significanty alter the product distribution in the photochemical reaction of VN, increasing the trans: cis ratio of 1,2-di(2-naphthyl)cyclobutane from 1 : 10 in the absence of amines to ca. 2 : 1 in the presence of 1,4-diazabicyclo[2.2.2]octane.Keywords
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