Phosphinimino-phosphoniumchloride mit P-P(P-As)-Bindung / Phosphinimino-phosphonium Chlorides with P-P(P-As) Bonds
Open Access
- 1 February 1974
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 29 (1-2) , 35-41
- https://doi.org/10.1515/znb-1974-1-213
Abstract
Desilylation reactions of N-trimethylsilyl-triorganophosphine imines with diorganochlorophosphines do not afford phosphinimino-phosphines, because a second mole of diorganochlorophosphine is immediately added yielding phosphinimino-phosphonium chlorides containing a phosporus-phosphorus bond. These phosphonium chlorides can also be obtained from phosphinimino-phosphines and diorganochlorophosphines. The latter route has been extended to prepare analogous compounds with a phosphorusarsenic bond. All new compounds were characterized by elemental analysis, and by IR 1H and 31P NMR spectra.Keywords
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