19F nuclear magnetic resonance studies of aromatic compounds. Part III. The transmission of substituent effects across bridged ring systems
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 13,p. 1988-1995
- https://doi.org/10.1039/p29720001988
Abstract
The synthesis of several series of bridged dinuclear aromatic compounds of the type p-F·C6H4·Z·C6H4·X-p[Z = all-trans-·CHCH–CHCH·, CCH2, CH2, CH(OH), CMe(OH), –O–, or –S–; X = NH2, OMe, H, F, Cl, or NO2] is described. The 19F n.m.r. spectra of these compounds are used to examine the ‘transmission’ of electronic effects, due to the group X, across the bridge Z. A distinction is drawn between ‘transmission effects’ in which electron density may be considered to be transferred from one ring to the other and ‘relay effects’ in which there is probably no net transfer of electron density.Keywords
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