Raman scattering by nanophase titanium dioxide

Abstract
Raman spectra of nanophase titanium dioxide are examined for different particle sizes and after successive annealing temperatures. All the normal modes at 152, 230-250, 422, 612, 702 and 796 cm-1 are assigned comparing with assignments for rutile, anatase structures and other nanophase TiO2. Oxygen deficient effect, grain-size effect and critical selection rule are specially discussed, which are related to special properties of the modes concerned.

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