Carbon-13 N.M.R. lanthanide-induced shift study of some D:A-friedooleananes
- 1 January 1984
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 37 (12) , 2571-2575
- https://doi.org/10.1071/ch9842571
Abstract
Carbon-13 n.m.r. signal assignments for D:A-friedooleanan-28-ol (1), D:A-friedooleanan-29-ol (2), D:A-friedooleanan-30-ol (3)D:a-friedooleanan-30-ol (4, D:A-friedooleanan-21α-ol (5) and 21α- hydroxy-D:A-friedooleanan-3-one (6) are reported. Lanthanide-induced shifts of the hydroxy compounds indicate that the oxygenation in the vicinity of ring E in these molecules does not affect the chair-chair-chair-twistboat-boat conformation proposed for D:A-friedooleananes.Keywords
This publication has 0 references indexed in Scilit: