Geometrische und chemische Koordination
- 1 February 1992
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Kristallographie - Crystalline Materials
- Vol. 201 (3-4) , 213-222
- https://doi.org/10.1524/zkri.1992.201.3-4.213
Abstract
Two geometrical concepts of coordination (Frank and Kasper 1958 and Ruban 1985) are identical with Niggli's (1927) concept of “Wirkungsbereich”. The geometrical coordination number can be reduced to a chemical coordination number which includes the number of weak bonds in the case of irregular coordinations or molecular compounds.Bond lengths in solid CO2, calcite, magnesite, rhodochrosite, siderite, smithonite and dolomite are discussed. Exceptionally short C – O-bonds in calcite are due to the large distance between carbonate layers which is caused by the larger ionic radius of Ca2+.Keywords
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