Heavy oxynitridation technology for forming highly reliable flash-type EEPROM tunnel oxide films

Abstract
For the first time, it is demonstrated that in flash-type EEPROMs, the endurance properties are dramatically improved by heavy oxynitridation (RTONO) of the tunnel oxide. The layer composition evaluted by SIMS measurement indicates that large amounts of N atoms (>1020 atom/cm3) pile up at the SiO2/Si interface, and are distributed in the bulk SiO2. In addition, the RTONO film reduces the number of hydrogen atoms, which are the origin of electron traps. This oxynitridation causes a decrease of both electron and hole traps in the tunnel oxide, resulting in an improvement of the threshold voltage narrowing.

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