SYNTHESIS AND CHARACTERIZATION OF TERMINALLY FUNCTIONALIZED n-ALKANETHIOLS
- 1 September 1996
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 116 (1) , 77-92
- https://doi.org/10.1080/10426509608040471
Abstract
Syntheses and characterization of a series of terminally functionalized n-alkanethiols with the general formula X-(CH2)n-SH are reported, where X─OH, NO2, CO2H, CO2Me, CO2Et, p-NO2-Ph, p-NH2-Ph, and n has a value between 5 and 12. These compounds are prepared for the synthesis of self-assembled monolayers on gold surfaces, which provides a simple approach to chemically modified surfaces with controlled interfacial structures.Keywords
This publication has 25 references indexed in Scilit:
- Vectorial electron transfer in flavolipid/ cytochrome c heterolayerJournal of Electroanalytical Chemistry, 1993
- Direct electron transfer reactions between immobilized cytochrome c and modified gold electrodesJournal of Electroanalytical Chemistry, 1993
- Photopatterning and selective electroless metallization of surface-attached ligandsChemistry of Materials, 1993
- Chromophoric self-assembled nonlinear optical multilayer materials. Synthesis, properties, and structural interconversions of assemblies with rodlike alkynyl chromophoresLangmuir, 1993
- Self-assembled monolayers of alkanethiols on gold: comparisons of monolayers containing mixtures of short- and long-chain constituents with methyl and hydroxymethyl terminal groupsLangmuir, 1992
- Comparisons of self-assembled monolayers on silver and gold: mixed monolayers derived from HS(CH2)21X and HS(CH2)10Y (X, Y = CH3, CH2OH) have similar propertiesLangmuir, 1991
- Biotin-functionalized self-assembled monolayers on gold: surface plasmon optical studies of specific recognition reactionsLangmuir, 1991
- Electron-transfer reaction of cytochrome c adsorbed on carboxylic acid terminated alkanethiol monolayer electrodesJournal of the American Chemical Society, 1991
- Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on AluminaScience, 1989
- Organized self-assembling monolayers on electrodes. 2. Monolayer-based ultramicroelectrodes for the study of very rapid electrode kineticsThe Journal of Physical Chemistry, 1987