Collapse of branched polymers
- 1 January 1983
- journal article
- Published by EDP Sciences in Journal de Physique
- Vol. 44 (12) , 1365-1376
- https://doi.org/10.1051/jphys:0198300440120136500
Abstract
Exact calculations using transfer matrices on finite strips are performed to study the two-dimensional problem of one lattice animal with an attractive nearest neighbour interaction. Thermodynamic quantities such as specific heat, compressibility, thermal expansion are calculated. Finite size scaling with two strips of different widths yields very accurate approximations of the critical line. Using three different strip widths or the two largest eigenvalues of the transfer matrix, we present two ways of obtaining the tricritical point and its exponents. Our estimations are quite stable when we increase the strip width and we can give rather accurate predictions. Lastly our model can also be interpreted as a gel whose parameters are temperature and pressure showing the experimentally known phenomenon of the collapseKeywords
This publication has 23 references indexed in Scilit:
- Test of scaling laws describing the concentration dependence of surface pressure of a polymer monolayerMacromolecules, 1982
- Properties of two-dimensional polymersMacromolecules, 1982
- Collapse of a polymer : evidence for tricritical behaviour in two dimensionsJournal de Physique, 1982
- A Monte Carlo study of the collapse of a polymer chainMacromolecules, 1981
- Phase Transition Behavior of the Isolated Polymer ChainMacromolecules, 1979
- First observation of the coil–globule transition in a single polymer chainNature, 1979
- Observation of the collapse of a polymer chain in poor solvent by small angle neutron scatteringThe Journal of Chemical Physics, 1978
- Collapse of a polymer chain in poor solventsJournal de Physique Lettres, 1975
- Phase transition in a polymer chain in dilute solutionPolymer, 1974
- Configuration and Free Energy of a Polymer Molecule with Solvent InteractionThe Journal of Chemical Physics, 1961