Synthesis and reactivity of (.eta.6-arene)(phosphino enolato)ruthenium(II) complexes, their coupling reaction with phenylacetylene and thermal rearrangement to a phosphametallacyclopropane. X-ray crystal structures of [cyclic] {Ru[.eta.3-CH:C(Ph)CH(PPh2)C(Bu-tert):O](p-cymene)}(PF6), of [cyclic] {Ru[.eta.3-CH:C(Ph)C(Me)(PPh2)C(Et):O](mesitylene)}(BF4), and of [cyclic] {Ru[.eta.3-CH(PPh2)CPh:C(H)C(Bu-tert):O](mesitylene)}(BF4)
- 1 October 1993
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 12 (10) , 3906-3917
- https://doi.org/10.1021/om00034a025
Abstract
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