The insertion of alkylgallium(I) groups [Ga–C(SiMe3)3] into P–P bonds of P4: formation of a P4(GaR)3 cage
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 9,p. 771-772
- https://doi.org/10.1039/a900670b
Abstract
The tetrahedral gallium(I) compound Ga4[C(SiMe3)3]4 1 reacted with white phosphorus by the threefold insertion of its monovalent gallium atoms into P–P bonds of the P4 tetrahedron with formation of a novel P4(GaR)3 cage possessing a structure similar to P4S3.Keywords
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