Abstract
Attempts to synthesize trichloro-substituted buta-1,3-diene-irontricarbonyl complexes are reported. While from trans-1,2-dichloro-3-chloro-buta-1,3-diene and trans-1,2-trans-4-trichloro-buta-1,3 -diene and triirondodekacarbonyl the correspondingly substituted tricarbonyl (buta-1,3-diene) iron complexes are obtained, 1,1-trans-4-trichloro-buta-1,3-diene under similar conditions does not form an irontricarbonyl complex.

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