13C‐NMR‐Spektroskopische Untersuchungen an Grignard‐Verbindungen
- 24 November 1972
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 763 (1) , 173-183
- https://doi.org/10.1002/jlac.19727630119
Abstract
In konzentrierten ätherischen Lösungen liegen Grignard‐Verbindungen überwiegend in der Form R2Mg + MgX2 vor. Die 13C‐chemischen Verschiebungen aliphatischer Grignard‐Verbindungen sind linear korrelierbar mit denen entsprechender Kohlenwasserstoffe. Allyl‐und Cyclopentadienylmagnesiumbromid zeigen austauschentartete 13C‐Spektren. Für alkyl‐substituierte Benzole konnten die Linien zugeordnet werden.Keywords
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