1,3-Shifts in fluxional η3-dienylpalladium(II) complexes
- 1 January 1976
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1058-1059
- https://doi.org/10.1039/c39760001058
Abstract
η 3 Cyclohepta-2,4-dienylpalladium complex are fluxional in solution owing to intercharge of C(1) and C(5), C(2) and C(4), and C(6) and C(7); a 1,3-shift mechanism is indicatred for the interchanges and there is a direct relation between ΔG‡ and the trans-effectiveness of L in [Pd(C7H9)L2] or [Pd(C7H9)L2]PF6.Keywords
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