The Platinum Complex-catalyzed Reductive N-Carbonylation of Dinitroarenes to the Biscarbamates
- 1 October 1984
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 57 (10) , 3011-3012
- https://doi.org/10.1246/bcsj.57.3011
Abstract
Dichlorobis(triphenylphosphine) platinum(II) shows good catalytic activity for the reductive N-carbonylation of dinitroarenes in ethanol in the presence of a Lewis acid and triethylamine. From 2,4-dinitrotoluene, diethyl 4-methyl-1,3-phenylenebiscarbamate is obtained in 50% yield at 190°C under carbon monoxide pressure of 60 kg cm−2.Keywords
This publication has 2 references indexed in Scilit:
- The Platinum Complex Catalyzed Reductive N-Carbonylation of Nitroarenes to the CarbamatesBulletin of the Chemical Society of Japan, 1983
- Synthesis of Nitrogen-containing Compounds by the Interaction of Nitro-compounds with Carbon MonoxideRussian Chemical Reviews, 1981