[H3Ru4(CO)12]–: the X-ray crystallographic determination of two structural isomers
- 1 January 1978
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 920-921
- https://doi.org/10.1039/c39780000920
Abstract
X-Ray analysis has shown the presence of two structural isomers of the [H3Ru4(CO)12]– anion with metal–hydrogen geometries approximating to C2 and C3v symmetry; although the presence of structural isomers has been postulated for several metal carbonyl hydrides, this work presents the first confirmation of their existence in the solid state.Keywords
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