ChemInform Abstract: Steroidal A Ring Aryl Carboxylic Acids: A New Class of Steroid 5α-Reductase Inhibitors.

Abstract
The 17β‐carbamoylestratriene‐3‐carboxylate (VIII) is prepared from estrone (I) by sequential introduction of carboxylate‐derived moieties at C‐3 and C‐17 using palladium(0) catalyzed carbonyl insertion.

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