Classical One Step Syntheses of Monoand Di-Nitrate Sugars via Triflates
Open Access
- 1 June 1984
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 39 (6) , 840-841
- https://doi.org/10.1515/znb-1984-0630
Abstract
A new approach for the synthesis of some sugar nitrates is described. The reaction sequence consists of esterifying partially protected carbohydrates with trifluoromethanesulfonic anhydride and reacting the resulting triflates with tetrabutylammonium nitrate. This procedure is mild, convenient and has the advantage of protecting highly acid-labile groups.Keywords
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