Nickel-Catalyzed β-Boration of α,β-Unsaturated Esters and Amides with Bis(pinacolato)diboron
- 1 November 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (24) , 5031-5033
- https://doi.org/10.1021/ol702254g
Abstract
A nickel catalyst system for β-boration of α,β-unsaturated esters and amides with bis(pinacolato)diboron has been developed. The catalyst system enables the boration of di-, tri-, and tetrasubstituted substrates in good yields.Keywords
This publication has 7 references indexed in Scilit:
- Alkylation of Aldehydes with Trialkylboranes in WaterAdvanced Synthesis & Catalysis, 2006
- Nickel-Catalyzed Alkylation of Aldehydes with TrialkylboranesOrganic Letters, 2005
- Synthesis and antifungal and antibacterial bioactivity of cyclic diamines containing boronate estersNew Journal of Chemistry, 2003
- A borylcopper species generated from bis(pinacolato)diboron and its additions to α,β-unsaturated carbonyl compounds and terminal alkynesJournal of Organometallic Chemistry, 2001
- Contemporary Boron ChemistryPublished by Royal Society of Chemistry (RSC) ,2000
- Palladium-Catalyzed Cross-Coupling Reactions of Organoboron CompoundsChemical Reviews, 1995
- Unusual coordination number and geometry in a potassium 18-crown-6 complexJournal of the American Chemical Society, 1992