Electronic transition moment of the N+2(A 2Πu–X 2Σ+g) system
- 1 February 1976
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 64 (3) , 1134-1139
- https://doi.org/10.1063/1.432301
Abstract
The variation of the electronic transition moment of the N+2 A 2Πu–X 2Σ+g system has been estimated using measured optical emission rates. The variation is nonlinear and may be described by the equation Re(r̄)/Re(1.0) =33.3[1.00−1.80r̄ +0.83r̄2], 1.02 Å⩽r̄⩽1.14 Å. An accurate transition probability table cannot be established due to lack of emission rate data in the near infrared. The variation of Re(r̄) cannot be obtained from lifetime measurements of the A 2Πu state.Keywords
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