The chemistry of the phosphoryl linkage: examples of P IV ? P V and P IV ? P VI transformation under mild conditions
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 321-322
- https://doi.org/10.1039/c39760000321
Abstract
Catechol and substituted catechols react with phosphonic acid or with phosphoryl chloride under mild conditions to give P-spirobis-(o-arylenedioxy)phosphoranes; where the non-cyclic substituent at phosphorus is a catechol residue the phosphoranes are readily transformed by organic bases into corresponding tris-(o-aryl-enedioxy)phosphate anions.Keywords
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