Hydroxylation of alkanes by molecular oxygen with dinuclear FeII macrocyclic complexes as catalysts
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1523-1524
- https://doi.org/10.1039/a804258f
Abstract
The iron(II) complexes of two new macrocyclic ligands: [24]RBPyBC (L24), a 24-membered macrocycle containing phenol, pyridine and amino donor groups, and [30]RBBPyBC (L30), a 30-membered macrocycle containing phenol, bipyridine, and amino donor groups, were found to be effective for the hydroxylation of alkanes, including cyclohexane and adamantane, with H2S as a two-electron reductant.Keywords
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