Migration of a hydride ligand to a difluorocarbene ligand bound to rhodium. The synthesis and crystal structure of RhCl2(CF2H)(PPh3)2
- 22 May 1990
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 388 (3) , 391-408
- https://doi.org/10.1016/0022-328x(90)85384-b
Abstract
No abstract availableKeywords
This publication has 27 references indexed in Scilit:
- Electrophilic cleavage of carbon-fluorine bonds in hydrido trifluoromethyl complexes of platinum(II) by proton acids. Synthesis of hydrido carbene and hydrido carbonyl derivatives and x-ray structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH[cyclic](COCH2CH2O)(PPh3)2]BF4 (298 K)Inorganic Chemistry, 1989
- Transition-metal dihalocarbene complexesChemical Reviews, 1988
- Fluoroorganometallic chemistry: carbon-fluorine bond activation in perfluorometallacyclopentane complexesOrganometallics, 1988
- Electrophilic halogen exchange between Lewis acids and transition-metal perfluoroalkyl complexes. Synthesis and characterization of transition-metal .alpha.-haloalkyl complexesOrganometallics, 1984
- Electrophilic addition of an osminim-bound chloromethylene ligand to the benzene ring of a triphenylphosphine ligand. Synthesis of metallacyclic and metallabicyclic complexes. X-Ray structures of [OsCl(CO)2(o-PPh2C6H4CHCl)(PPh3)] and [OsCl(CO)2(o-PPh2C6H4CHC6H4PPh2-o)]Journal of the Chemical Society, Chemical Communications, 1984
- Facile electrophilic halogen exchange between boron trihalides and transition-metal perfluoroalkyl complexes. A novel method for the synthesis of reactive transition-metal haloalkyl complexesOrganometallics, 1983
- Oxidation state control of the reactivity of a transition metal–carbon double bond. Synthesis, X-ray crystal structure, and reactions of the zerovalent difluorocarbene complex [Ru(CF2)(CO)2(PPh3)2]Journal of the Chemical Society, Chemical Communications, 1983
- Difluorocarbene complexes of ruthenium derived from trifluoromethyl compounds. RuCl2(CF2)(CO)(PPh3)2, RuCl2(CFNMe2)(CO)(PPh3)2, RuCl2(CFOMe)(CO)(PPh3)2 and the structure of Ru(CF3)(HgCF3)(CO)2(PPh3)2Journal of Organometallic Chemistry, 1982
- Molybdenum perfluorocarbene complexesJournal of Organometallic Chemistry, 1978
- Übergangsmetall—carben-komplexe : LXXXVIII. Chlordiäthylaminocarben-pentacarbonyl-chromJournal of Organometallic Chemistry, 1976