Derivatives of pentacarbonylnitratorhenium(I) with some nitrogen, phosphorus, and arsenic donor ligands
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 19,p. 2070-2071
- https://doi.org/10.1039/dt9740002070
Abstract
Reactions of pentacarbonylnitratorhenium(I) with pyridine (py), 2,2′-bipyridyl (bipy), 2,2′2″-terpyridyl (terpy), triphenylphosphine, and triphenylarsine yield the fac-disubstituted derivatives, Re(CO)3L2NO3, in which the covalent metal–nitrate bond is retained. Tricarbonylnitratobis(triphenylphosphine)rhenium(I) has been shown to exhibit fac–mer isomerisation.Keywords
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