Benzylideneaniline. II. Iodine Complexes of Benzylideneaniline and its Derivatives
- 1 April 1960
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 33 (4) , 540-543
- https://doi.org/10.1246/bcsj.33.540
Abstract
Absorption spectra of the mixtures of iodine with benzylideneanilines in various concentrations have been measured, and from the optical densities of the solutions the equilibrium constants have been calculated. The equilibrium constants are unexpectedly small. But for methoxy-derivatives and especially for ortho-compound, the equilibrium constants are considerably large. For o-methoxy- and o-chloro-derivatives, the charge-transfer bands appear at the longer wavelengths. These experimental evidences are also adequately explained by the perpendicular structure of benzylideneaniline.This publication has 17 references indexed in Scilit:
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