On the loss of ethylene from [C3H7O]+ ions of structure \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm CH}_{\rm 3} {\rm CH}_{\rm 2} \mathop {{\rm CHOH}}\limits^{\rm + } $\end{document}
- 1 November 1979
- journal article
- research article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 14 (11) , 606-608
- https://doi.org/10.1002/oms.1210141107
Abstract
The results of some 3C and 2H labelling experiments plus some measurements of reaction thermochemistry and translational energy releases, permit a significant simplification of the mechanistic pathways by which [C3H7O]+ ions of structure equation image fragment by loss of C2H4. The relationships between these ions and some of their isomeric forms are explored and clarified.Keywords
This publication has 4 references indexed in Scilit:
- Structure and formation of gaseous [C4H5O]+ ions. I—isomeric ions of the type C3H5\documentclass{article}\pagestyle{empty}\begin{document} $\mathop {\rm C}\limits^ + =\!= $\end{document}OJournal of Mass Spectrometry, 1979
- Potential energy profiles for unimolecular reactions of organic ions: [C3H8N]+ and [C3H7O]+Journal of Mass Spectrometry, 1978
- Detailed potential energy surfaces for carbonium ion rearrangements: C3H7O+Journal of the American Chemical Society, 1977
- Formation of ruthenium(II) nitrile complexes by reaction of hexaammineruthenium(III) with aldehydesJournal of the American Chemical Society, 1975