Synthesis of optically active allenes using tandem enzyme and palladium-catalysed reactions
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2083-2084
- https://doi.org/10.1039/a704374k
Abstract
The propargylic carbonates (S)-6 and (R)-9 are converted into the chiral allenes 10, 11, 13 and 14 (ee 82–85%) using organozinc reagents and tetrakis(triphenylphosphine)- palladium as catalyst.Keywords
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