PREPARATION AND SOME PROPERTIES OF POLYTHIA[n]FERROCENOPHANES
- 5 November 1982
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 11 (11) , 1753-1756
- https://doi.org/10.1246/cl.1982.1753
Abstract
Polythiaferrocenophanes, 5, and 8–12, were prepared from 1,1′-ferrocenedithiol. Of these compounds, 1,4,7-trithia[7]ferrocenophane 8 showed an abnormal bathochromic shift in the electronic spectrum, and a downfield shift of the bridge-head carbons and an upfield shift of the other cyclopentadienyl carbons in the 13C-NMR spectrum. Compounds 9–12 also showed complexing affinity to silver ion according to the size of polythia-macrocycles.This publication has 7 references indexed in Scilit:
- Macrocyclic ligand ring size effects on complex stabilities and kinetics. Copper(II) complexes of cyclic polythiaethersJournal of the American Chemical Society, 1975
- Symmetrically disubstituted ferrocenes : I. The synthesis of potential bidentate ligandsJournal of Organometallic Chemistry, 1971
- Macrocyclic polyether sulfidesThe Journal of Organic Chemistry, 1971
- Octahedral nickel(II) complexes of some cyclic polyfunctional thioethersInorganic Chemistry, 1970
- Bridged ferrocenes—IITetrahedron, 1968
- Chemistry of metallocenes. I. Carbonium ion stabilization by the ferrocenyl groupJournal of the American Chemical Society, 1967
- Comprehensive Investigation of the Electronic Spectroscopy and Theoretical Treatments of Ferrocene and NickeloceneThe Journal of Chemical Physics, 1961