Interaction of di-t-butyl nitroxide with alkanols: e.s.r. measurements
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 73, 430-433
- https://doi.org/10.1039/f19777300430
Abstract
The 14N hyperfine coupling constant in di-t-butyl nitroxide dissolved in ethanol + carbon tetrachloride mixtures depends on the solvent composition. The analysis of the effect in terms of hydrogen-bonding between the radical and ethanol, and self-association of the latter, is discussed. Coupling constants for the radical in seven simple alkanols are reported.Keywords
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