New adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine and their vibrational, magnetic, and electronic properties. Part I. Reactivity towards oxygen
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 7,p. 556-561
- https://doi.org/10.1039/dt9750000556
Abstract
Different reaction temperatures have allowed the isolation of 1 : 1 and 1 : 2 adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine. Thermal, vibrational, and magnetic-susceptibility analyses have provided useful information about the structural properties of these complexes; e.s.r. and electronic spectra have permitted a detailed investigation of the ligand-field levels of the cobalt atom. All the adducts react with oxygen and form, at low temperatures, well characterized Co : O2 1 : 1 adducts.Keywords
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