Heats of vaporization and gaseous heats of formation of some five- and six-membered ring alkenes

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Abstract
The heats of vaporization of 1-methylcyclopentene, 3-methylcyclopentene, ethylidenecyclopentane, 1-ethylcyclopentene, methylenecyclohexane, allylcyclopentane, vinylcyclohexane, ethylidenecyclohexane, allylcyclohexane, 3,3-diethylpentane, 2,2,4,4-tetramethylpentane, and trans-2,2,5,5-tetramethyl-3-hexene have been measured by the gas chromatography – calorimetry method. These values have been combined with previously reported liquid heats of formation to give gaseous values of ΔHf. The results indicate that the internal double bond is favored by about 0.5 kcal over the exo in both 5- and 6-membered rings, but the endo–exo differences are much smaller than previously believed. Several of the liquid heat capacities that were measured were not well predicted by group additivity schemes.

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